J 2023

Synthesis of Enantiomerically Pure Bambus[6]urils Utilizing Orthogonal Protection of Glycolurils

SLÁVIK, Petr; Jacopo TORRISI; Pia Yasmine JURČEK; Jan SOKOLOV; Vladimír ŠINDELÁŘ et. al.

Basic information

Original name

Synthesis of Enantiomerically Pure Bambus[6]urils Utilizing Orthogonal Protection of Glycolurils

Authors

SLÁVIK, Petr (203 Czech Republic, belonging to the institution); Jacopo TORRISI (380 Italy, belonging to the institution); Pia Yasmine JURČEK (246 Finland, belonging to the institution); Jan SOKOLOV (203 Czech Republic, belonging to the institution) and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution)

Edition

Journal of Organic Chemistry, WASHINGTON, AMER CHEMICAL SOC, 2023, 0022-3263

Other information

Language

English

Type of outcome

Article in a journal

Country of publisher

United States of America

Confidentiality degree

is not subject to a state or trade secret

References:

RIV identification code

RIV/00216224:14310/23:00131646

Organization

Přírodovědecká fakulta – Repository – Repository

UT WoS

001039563400001

EID Scopus

2-s2.0-85167821150

Keywords in English

FLUORINATED BAMBUSURILS; DEPROTECTION; RECOGNITION; CUCURBITURIL; CATALYSTS; BINDING; WATER; ALKYL

Links

EF17_043/0009632, research and development project. GA23-05271S, research and development project. LM2018121, research and development project. MUNI/A/1209/2022, interní kód Repo. 857560, interní kód Repo. CIISB II, large research infrastructures.
Changed: 10/10/2024 00:50, RNDr. Daniel Jakubík

Abstract

V originále

amp; PRIME;-disubstitutedglycoluril enantiomers on a multigramscale using orthogonal protection is reported. The use of these glycolurilsis demonstrated in the synthesis of enantiomerically pure bambus[6]urilmacrocycles. Moreover, the deprotection of (S)-1-phenylethylsubstituents on the macrocycle was achieved, opening access to variouschiral bambus[6]urils via post-macrocyclization modificationstrategy.

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