J
2024
Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle
DEL MAURO, Arico; Jana LAPEŠOVÁ; Carola RANDO and Vladimír ŠINDELÁŘ
Basic information
Original name
Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle
Authors
DEL MAURO, Arico; Jana LAPEŠOVÁ; Carola RANDO and Vladimír ŠINDELÁŘ
Edition
Organic Letters, WASHINGTON, American Chemical Society, 2024, 1523-7060
Other information
Type of outcome
Article in a journal
Country of publisher
United States of America
Confidentiality degree
is not subject to a state or trade secret
Marked to be transferred to RIV
Yes
RIV identification code
RIV/00216224:14310/24:00135408
Organization
Přírodovědecká fakulta – Repository – Repository
Keywords in English
Anions; Carboxyls; Cavities; Macrocycles; Supramolecular chemistry
Links
EF17_043/0009632, research and development project. GA23-05271S, research and development project. MUNI/A/1604/2023, interní kód Repo. 857560, interní kód Repo. RECETOX RI, large research infrastructures. CIISB II, large research infrastructures. CZ-OPENSCREEN IV, large research infrastructures.
In the original language
Bambus-[6]-urils and biotin[6]-urils are macrocycles with an exceptional affinity for inorganic anions. Here, we investigated statistical condensation of 2,4-dibenzylglycoluril and d-biotin, monomers of the corresponding macrocycles, to prepare the enantiomerically pure macrocycle 1 containing a single d-biotin and five glycoluril units. Host-guest properties of 1 in chloroform solution and solid state were investigated. The macrocycle 1 bearing a single functional group was employed in the formation of [1]-rotaxane utilizing reversible covalent bonds.
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